PlanetPhysics/Magnetic Susceptibility

From testwiki
Jump to navigation Jump to search

In [[../Electromagnetism/|Electromagnetism]], the volume magnetic susceptibility , represented by the symbol χv is defined by the following equation

M=χvH, where in SI units M is the magnetization of the material (defined as the magnetic dipole moment per unit [[../Volume/|volume]], measured in amperes per meter), and H is the strength of the [[../NeutrinoRestMass/|magnetic field]] H, also measured in amperes per meter.

On the other hand, the magnetic induction B is related to H by the equation

B = μ0(H+M) = μ0(1+χv)H = μH, where μ0 is the magnetic constant, and  (1+χv) is the relative permeability of the material.

Note that the magnetic susceptibility χv and the magnetic permeability μ of a material are related as follows:

μ=μ0(1+χv).

There are two other measures of susceptibility, the mass magnetic susceptibility , χg or χm, and the molar magnetic susceptibility , χmol:

χ=mass==χv/ρ, χmol=Mχm=Mχv/ρ,

where ρ is the density and M is the molar [[../CosmologicalConstant/|mass]].

Susceptibility Sign convention

If χ is positive, then (1+χv)>1 (or, in cgs units, (1+4πχv)>1) and the material can be paramagnetic, ferromagnetic, ferrimagnetic, or anti-ferromagnetic; then, the magnetic field inside the material is strengthened by the presence of the material, that is, the magnetization value is greater than the external H-value.

On the other hand there are certain materials--called diamagnetic -- for which χ negative, and thus Failed to parse (syntax error): {\displaystyle (1+χv) < 1} (in SI units).

Magnetic Susceptibility Tensor, χ

The magnetic susceptibility of most crystals (that are anisotropic) cannot be represented only by a [[../Vectors/|scalar]], but it is instead representable by a [[../Tensor/|tensor]] χ . Then, the crystal magnetization M is dependent upon the orientation of the sample and can have non-zero values along directions other than that of the applied magnetic field H. Note that even non-crystalline materials may have a residual anisotropy, and thus require a similar treatment.

In all such magnetically anisotropic materials, the volume magnetic susceptibility tensor is then defined as follows:

Mi=χijHj,

where i and j refer to the directions (such as, for example, x, y, z in Cartesian coordinates) of, respectively, the applied magnetic field and the magnetization of the material. This rank 2 tensor (of dimension (3,3)) relates the component of the magnetization in the i-th direction, Mi to the component Hj of the external magnetic field applied along the j-th direction.

All Sources

[1] [2] [3] [2] [4] [5] [6] [7] [8] [9]

References

  1. G. P. Arrighini, M. Maestro, and R. Moccia (1968). Magnetic Properties of Polyatomic Molecules: Magnetic Susceptibility of H2O,NH3,CH4,H2O2. J. Chem. Phys. 49: 882-889. doi:10.1063/1.1670155.
  2. 2.0 2.1 S. Otake, M. Momiuchi and N. Matsuno (1980). Temperature Dependence of the Magnetic Susceptibility of Bismuth. J. Phys. Soc. Jap. 49 (5): 1824-1828. doi:10.1143/JPSJ.49.1824. Cite error: Invalid <ref> tag; name "OMM80" defined multiple times with different content
  3. J. Heremans, C. H. Olk and D. T. Morelli (1994). Magnetic Susceptibility of Carbon Structures. Phys. Rev. B 49 (21): 15122-15125. doi:10.1103/PhysRevB.49.15122.
  4. R. Dupree and C. J. Ford (1973). Magnetic susceptibility of the noble metals around their melting points. Phys. Rev. B 8 (4): 1780–1782. doi:10.1103/PhysRevB.8.1780. ====Magnetic Moments and Nuclear Magnetic Resonance Spectrometry====
  5. J. R. Zimmerman, and M. R. Foster (1957). Standardization of NMR high resolution spectra. J. Phys. Chem. 61: 282-289. doi:10.1021/j150549a006.
  6. Robert Engel, Donald Halpern, and Susan Bienenfeld (1973). Determination of magnetic moments in solution by nuclear magnetic resonance spectrometry. Anal. Chem. 45: 367-369. doi:10.1021/ac60324a054.
  7. P. W. Kuchel, B. E. Chapman, W. A. Bubb, P. E. Hansen, C. J. Durrant, and M. P. Hertzberg (2003). Magnetic susceptibility: solutions, emulsions, and cells. Concepts Magn. Reson. A 18: 56-71. doi:10.1002/cmr.a.10066.
  8. K. Frei and H. J. Bernstein (1962). Method for determining magnetic susceptibilities by NMR. J. Chem. Phys. 37: 1891-1892. doi:10.1063/1.1733393.
  9. R. E. Hoffman (2003). Variations on the chemical shift of TMS. J. Magn. Reson. 163: 325-331. doi:10.1016/S10907807(03)001423.

Template:CourseCat