Waves in composites and metamaterials/Fresnel equations

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The content of these notes is based on the lectures by Prof. Graeme W. Milton (University of Utah) given in a course on metamaterials in Spring 2007.

A brief excursion into homogenization

One of the first questions that arise in the homogenization of composites is whether determining the effective behavior of the composite by some averaging process is the right thing to do. At this stage we ignore such questions and assume that there is a representative volume element (RVE) over which such an average can be obtained.

Let 𝐄 be an average over some RVE of the 𝐄-field at an atomic scale. Similarly, let 𝐁 be the average of the 𝐁-field. Recall, from the previous lecture, that the Maxwell equations have the form (we have dropped the hats over the field quantities)

×𝐄=iωμ(𝐱,ω)𝐇(𝐱);×𝐇=iωϵ(𝐱,ω)𝐄(𝐱).

For some conductors, at low frequencies, the permittivity tensor is given by

ϵϵ0+iωσ

where ϵ0 is the real part of the permittivity tensor and σ is the electrical conductivity tensor. [1]

A mixture of conductors and dielectric materials may have properties which are quite different from those of the constituents. For example, consider the checkerboard material shown in Figure 1 containing an isotropic conducting material and an isotropic dielectric material.

File:CheckerBoardMaterial.jpg
Figure 1. Checkerboard material containing conducting and dielectric phases.

The conducting material has a permittivity of ϵ1=1+iσ/ω while the dielectric material has a permittivity of ϵ2=1. The effective permittivity of the checkerboard is given by

ϵeff=ϵ1ϵ2=1+iσωiσω(for smallω)a+ibfor anya,b.

Plane waves

Let us assume that the material is isotropic. Then,

𝑹Tϵ𝑹=ϵand𝑹Tμ𝑹=μrotations𝑹T𝑹=𝑹𝑹T=1.

Therefore, we can write

ϵ=ϵ1andμ=μ1.

The Maxwell equations then take the form

(2)×𝐄=iωμ(𝐱,ω)𝐇(𝐱);×𝐇=iωϵ(𝐱,ω)𝐄(𝐱).

If we assume that μ and ϵ do not depend upon position, i.e., μμ(ω) and ϵϵ(ω), and take the curl of equations (2), we get

×(×𝐄)=iωμ×𝐇=ω2ϵμ𝐄(𝐱);×(×𝐇)=iωϵ×𝐄=ω2ϵμ𝐇(𝐱).

Using the identity ×(×𝐀)=(𝐀)2𝐀, we get

(3)(𝐄)2𝐄=ω2ϵμ𝐄(𝐱);(𝐇)2𝐇=ω2ϵμ𝐇(𝐱).

Since

𝐁=0;𝐃=0;𝐇(𝐱)=μ1(ω)𝐁(𝐱);𝐃(𝐱)=ϵ(ω)𝐄(𝐱)

we have

𝐇=μ1𝐁=0and𝐄=ϵ1𝐃=0.

Therefore, from equation (3), we have

2𝐄+ω2ϵμ𝐄(𝐱)=0;2𝐇+ω2ϵμ𝐇(𝐱)=0.

We can also write the above equations in the form

(4)2𝐄+κ2𝐄(𝐱)=0;2𝐇+κ2𝐇(𝐱)=0whereκ2=ω2c2andc2=1ϵμ

where c is the phase velocity (the velocity at which the wave crests travel). To have a propagating wave, c must be real. This will be the case when ϵ and μ are both positive or both negative (see Figure 2).

File:MuEpsPlane.jpg
Figure 2. Transparency and opacity of a material as a function ofμ and ϵ.


Let us look for plane wave solutions to the equations (4) of the form

(5)𝐄(𝐱)=𝐄0ei(𝐀𝐱)

where |𝐀|=1/(2πλ) and λ is the wavelength. Then, using the first of equations (2) we have

(6)𝐇(𝐱)=iωμ×𝐄=1ωμ𝐀×𝐄0ei(𝐀𝐱)=𝐇0ei(𝐀𝐱)

where 𝐇0=1/(ωμ)𝐀×𝐄0.

Since 𝐄=0, we have (in terms of components with respect to a orthonormal Cartesian basis)

𝐄=xm[E0mei(klxl)]=iklxlxmE0mei(klxl)=ikmE0mei(klxl)=i(𝐀𝐄0)ei(𝐀𝐱)=0.

Hence,

𝐀𝐄0=0.

Similarly, since 𝐇=0, we have

𝐇=1ωμ[xm(β„°mpqkpE0qei(klxl))]=iωμ[β„°mpqkpE0qkmei(klxl)]=iωμ𝐀(𝐀×𝐄0)ei(𝐀𝐱).

Hence,

𝐀𝐇0=0.

Plugging equation (5) into the first of equations (4) we get

[2𝐄+κ2𝐄(𝐱)]n=xm[xm(E0neiklxl)]+κ2E0neiklxl=xm[E0n(iklxlxm)eiklxl]+κ2E0neiklxl=iE0nkmxm(eiklxl)+κ2E0neiklxl=iE0nkm(iklxlxm)eiklxl+κ2E0neiklxl=E0nkmkmeiklxl+κ2E0neiklxl.

Reverting back to Gibbs notation, we get

(𝐀𝐀)𝐄0ei(𝐀𝐱)+κ2𝐄0ei(𝐀𝐱)=0.

Therefore,

𝐀𝐀=κ2.

Plugging the solution (6) into the second of equations (4) (and using index notation as before) we get

[2𝐇+κ2𝐇(𝐱)]n=1ωμ{xm[xm(β„°npqkpE0qeiklxl)]+κ2β„°npqkpE0qeiklxl}=1ωμ{xm[β„°npqkpE0q(iklxlxm)eiklxl]+κ2β„°npqkpE0qeiklxl}=1ωμ{iβ„°npqkpkmE0q[iklxlxm]eiklxl+κ2β„°npqkpE0qeiklxl}=1ωμ{β„°npqkpkmkmE0qeiklxl+κ2β„°npqkpE0qeiklxl}

In Gibbs notation, we then have

2𝐇+κ2𝐇(𝐱)=1ωμ(𝐀𝐀+κ2)𝐀×𝐄0ei(𝐀𝐱)=0.

Therefore, once again, we get

𝐀𝐀=κ2.

Reflection at an Interface

The following is based on the description given in [Lorrain88]. Figure 3 shows an electromagnetic wave that is incident upon an interface separating two mediums.

File:ReflectInt.jpg
Figure 3. Reflection of an electromagnetic wave at an interface.

We ignore the time-dependent component of the electric fields and assume that we can express the waves shown in Figure 3 in the form

𝐄i=𝐄0iei(𝐀i𝐱)𝐄r=𝐄0rei(𝐀r𝐱)𝐄t=𝐄0tei(𝐀t𝐱)

where 𝐀i,𝐀r,𝐀t are the wave vectors.

Since the oscillations at the interface must have the same period (the requirement of continuity), we must have

𝐀i𝐱=𝐀r𝐱=𝐀t𝐱𝐱on the interface.

This means that the tangential components of 𝐀i,𝐀r,𝐀t must be equal at the interface. Therefore,

|𝐀i|sinθi=|𝐀r|sinθr=|𝐀t|sinθt.

Now,

|𝐀i|=κi=ωc1;|𝐀r|=κr=ωc1;|𝐀t|=κt=ωc2

where c1 and c2 are the phase velocities in medium 1 and medium 2, respectively. Hence we have,

ωc1sinθi=ωc1sinθr=ωc2sinθt.

This implies that

θi=θrandsinθisinθt=c1c2.

The refractive index is defined as

n:=c0c

where c0 is the phase velocity is vacuum. Therefore, we get

sinθisinθt=n2n1(Snells Law).

Polarized wave with the Ei parallel to the plane of incidence

Consider the p-polarized wave shown in Figure 4. The figure represents an infinite wave polarized with the 𝐄i vector polarized parallel to the plane of incidence. This is also called the TM (transverse magnetic) case.

File:PPolarized.jpg
Figure 4. Infinite wave polarized with the 𝐄i-vector parallel to the plane of incidence.

Let us define

κ1:=|𝐀i|=|𝐀r|andκ2:=|𝐀t|.

Recall that,

𝐄i(𝐱)=𝐄0iei(𝐀i𝐱)𝐄r(𝐱)=𝐄0rei(𝐀r𝐱)𝐄t(𝐱)=𝐄0tei(𝐀t𝐱)

Let us choose an orthonormal basis (𝐞1,𝐞2,𝐞3) such that the 𝐞1 vector lies on the interface and is parallel the plane of incidence. The 𝐞2 vector lies on the plane of incidence and the 𝐞3 vector is normal to the interface. Then the vectors 𝐀i, 𝐀r, and 𝐀t may be expressed in this basis as

𝐀i=κ1sinθi𝐞1κ1cosθi𝐞3𝐀r=κ1sinθr𝐞1+κ1cosθr𝐞3𝐀t=κ2sinθt𝐞1κ2cosθt𝐞3.

Similarly, defining

β„°i:=|𝐄0i|;β„°r:=|𝐄0r|;β„°t:=|𝐄0t|

we get

𝐄0i=β„°icosθi𝐞1+β„°isinθi𝐞3𝐄0r=β„°rcosθr𝐞1+β„°rsinθr𝐞3𝐄0t=β„°tcosθt𝐞1+β„°tsinθt𝐞3.

Using the definition

𝐇0:=1ωμ𝐀×𝐄0

we then get

𝐇0i=κ1ωμ1β„°i𝐞2β„‹i:=|𝐇0i|=κ1β„°iωμ1𝐇0r=κ1ωμ1β„°r𝐞2β„‹r:=|𝐇0r|=κ1β„°rωμ1𝐇0t=κ2ωμ2β„°t𝐞2β„‹t:=|𝐇0t|=κ2β„°tωμ2.

Hence, with the vector 𝐱 expressed as 𝐱=x1𝐞1+x2𝐞2+x3𝐞3, we get

𝐄i(𝐱)=(β„°icosθi𝐞1+β„°isinθi𝐞3)ei[κ1(x1sinθix3cosθi)]𝐄r(𝐱)=(β„°rcosθr𝐞1+β„°rsinθr𝐞3)ei[κ1(x1sinθr+x3cosθr)]𝐄t(𝐱)=(β„°tcosθt𝐞1+β„°tsinθt𝐞3)ei[κ2(x1sinθtx3cosθt)].

Similarly,

𝐇i(𝐱)=β„‹i𝐞2ei[κ1(x1sinθix3cosθi)]𝐇r(𝐱)=β„‹r𝐞2ei[κ1(x1sinθr+x3cosθr)]𝐇t(𝐱)=β„‹t𝐞2ei[κ2(x1sinθtx3cosθt)].

At the interface, continuity requires that the tangential components of the vectors 𝐄 and 𝐇 are continuous. Clearly, from the above equations, the 𝐇0 vectors are tangential to the interface. Also, at the interface x3=0 and x1 is arbitrary. Hence, continuity of the components of 𝐇 at the interface can be achieved if

β„‹i+β„‹r=β„‹t.

In terms of the electric field, we then have

κ1ωμ1β„°i+κ1ωμ1β„°r=κ2ωμ2β„°t.

Recall that the refractive index is given by n=c0/c=c0κ/ω. Therefore, we can write the above equation as

(7)n1μ1(β„°i+β„°r)=n2μ2β„°t.

The tangential components of the 𝐄 vectors at the interface are given by 𝐄×𝐞3. Therefore, the tangential components of the 𝐄0 vectors at the interface are

𝐄0i×𝐞3=β„°icosθi𝐞2𝐄0r×𝐞3=β„°rcosθr𝐞2𝐄0t×𝐞3=β„°tcosθt𝐞2.

Using the arbitrariness of x1 and from the continuity of the 𝐄 vectors at the interface, we have

β„°icosθiβ„°rcosθr=β„°tcosθt.

Since θi=θr, we have

(8)(β„°iβ„°r)cosθi=β„°tcosθt.

From equations (7) and (8), we get two more relations:

(9)β„°rβ„°i=n2μ2cosθin1μ1cosθtn2μ2cosθi+n1μ1cosθt

and

(10)β„°tβ„°i=2n1μ1cosθin2μ2cosθi+n1μ1cosθt.

Equations (7), (8), (9), and (10) are the Fresnel equations for p-polarized electromagnetic waves.

If we define,

μr1:=μ1μ0andμr2:=μ2μ0

where μ0 is the permeability of vacuum, then we can write equations (9) and (10) as

(11)β„°rβ„°i=n2μr2cosθin1μr1cosθtn2μr2cosθi+n1μr1cosθt;β„°tβ„°i=2n1μr1cosθin2μr2cosθi+n1μr1cosθt.

Note that

n2μr2cosθi=n1μr1cosθtβ„°r=0.

For non-magnetic materials we have μr1=μr2=1. Hence,

(12)n2n1=cosθtcosθi.

Also, from Snell's law

(13)n2n1=sinθisinθt.

Combining equations (12) and (13), we get

cosθtsinθtcosθisinθi=0sin(2θt)sin(2θi)=0cos(θt+θi)sin(θtθi)=0.

If n1n2 we have sin(θtθi)0. Hence,

(14)cos(θt+θi)=0θt+θi=π2.

This is the condition that defines Brewster's angle (θi=θB). Plugging equation (14) into equation (13), we get

sinθBsin(π/2θB)=tanθB=n2n1.

This relation can be used to solve for Brewster's angle for various media. At Brewster's angle, we have

β„°rβ„°i=n2μr2cosθBn1μr1sinθBn2μr2cosθB+n1μr1sinθB=0.

Hence, the sign of β„°r/β„°i changes at the Brewster angle.

Also, note that if n2=n1 and μ2=μ1, since n=c0ϵμ we must have ϵ2=ϵ1. Then, by Snell's law

sinθtsinθi=1θt=θi.

Hence,

β„°rβ„°i=n1μr1cosθin1μr1cosθin1μr1cosθi+n1μr1cosθi=0andβ„°tβ„°i=2n1μr1cosθin1μr1cosθi+n1μr1cosθi=1.

So the radiation is transmitted at the angle θt=θi and none is reflected.

More can be said about the matter. In fact, an interface separating media with ϵ2=ϵ1 and μ2=μ1 "behaves like a mirror". Consider the interface in Figure 5. Suppose that on the left side of the mirror, 𝐄 and 𝐇 solve Maxwell's equations

×𝐄+iωμ1𝐇=0;×𝐇iωϵ1𝐄=0.

Let the solution be of the form

𝐄(𝐱)=[E1(𝐱),E2(𝐱),E3(𝐱)]and𝐇(𝐱)=[H1(𝐱),H2(𝐱),H3(𝐱)].

Suppose that the right hand side of the interface has reflected fields, i.e.,

𝐄(𝐱)=[E1(x1,x2,x3),E2(x1,x2,x3),E3(x1,x2,x3)]and𝐇(𝐱)=[H1(x1,x2,x3),H2(x1,x2,x3),H3(x1,x2,x3)].
File:MirrorNegativeRefract.jpg
Figure 5. Reflection at an interface due to negative ϵ and μ.

Also, on the right hand side, let

×𝐄=[F1(𝐱),F2(𝐱),F3(𝐱)].

Then, to the right of the interface, we have

×𝐄={[x2[E3(x1,x2,x3)]x3[E2(x1,x2,x3)]],[x3[E1(x1,x2,x3)]+x1[E3(x1,x2,x3)]],[x1[E2(x1,x2,x3)]+x2[E1(x1,x2,x3)]]}

or,

×𝐄=[F1(x1,x2,x3),F2(x1,x2,x3),F3(x1,x2,x3)].

Polarized wave with the Ei perpendicular to the plane of incidence

For a plane polarized wave with the 𝐄i vector perpendicular to the plane of incidence, we have

𝐄0i=β„°i𝐞2𝐄0r=β„°r𝐞2𝐄0t=β„°t𝐞2.

Therefore,

𝐇0i=κ1ωμ1(β„°icosθi𝐞1+β„°isinθi𝐞3)𝐇0r=κ1ωμ1(β„°rcosθr𝐞1+β„°rsinθr𝐞3)𝐇0t=κ2ωμ2(β„°tcosθt𝐞1+β„°tsinθt𝐞3).

Continuity of tangential components of 𝐄 at the interface gives

(15)β„°i+β„°r=β„°t.

The tangential components of 𝐇0 at the interface are given by

𝐇0i×𝐞3=κ1ωμ1β„°icosθi𝐞2𝐇0r×𝐞3=κ1ωμ1β„°rcosθr𝐞2𝐇0t×𝐞3=κ2ωμ2β„°tcosθt𝐞2.

From continuity at the interface and using the arbitrariness of x1, we get (from the above equations with θi=θr)

κ1ωμ1(β„°iβ„°r)cosθi=κ2ωμ1β„°tcosθt.

Using the relation κ=nω/c0, we get

(16)n1μ1(β„°iβ„°r)cosθi=n2μ2β„°tcosθt.

From equations (15) and (16), we get

(17)β„°rβ„°i=n1μ1cosθin2μ2cosθtn1μ1cosθi+n2μ2cosθt

and

(18)β„°tβ„°i=2n1μ1cosθin1μ1cosθi+n2μ2cosθt.

Equations (15), (16), (17), and (18) are the Fresnel equations a wave polarized with the 𝐄i vector perpendicular to the plane of incidence. We may also write the last two equations as

(19)β„°rβ„°i=n1μr1cosθin2μr2cosθtn1μr1cosθi+n2μr2cosθt;β„°tβ„°i=2n1μr1cosθin1μr1cosθi+n2μr2cosθt.

From the above equations, there is no reflected wave only if

tanθi=tanθtμ1μ2.

This is only possible if there is no interface. Therefore, in the presence of a interface, there is always a reflected wave for this situation.

Footnotes

  1. ↑ The above relation for the permittivity tensor can be obtained as follows. Recall that
    𝐃~(𝐱,t)=𝐃(𝐱,t)+t𝐉f(𝐱,τ)dτ.
    Differentiating the above relation with respect to time, we get
    𝐃~t=𝐃t+𝐉f(𝐱,t).
    Assuming harmonic solutions of the form
    𝐃~(𝐱,t)=𝐃~^(𝐱)exp(iωt);𝐃(𝐱,t)=𝐃^(𝐱)exp(iωt);𝐉f(𝐱,t)=𝐉^f(𝐱)exp(iωt);𝐄(𝐱,t)=𝐄^(𝐱)exp(iωt)
    and plugging into the differential equation above, we get
    (iω)𝐃~^(𝐱)=(iω)𝐃^(𝐱)+𝐉^f(𝐱).
    Now, the free current density 𝐉f and the electric displacement 𝐃 are related to the electric field 𝐄 by
    (1)𝐉f=σ𝐄;𝐃=ϵ0𝐄.
    Therefore,
    𝐃~^(𝐱)=ϵ0𝐄^(𝐱)+iωσ𝐄^(𝐱)=ϵ𝐄^(𝐱)
    where
    ϵ=ϵ0+iωσ.

References

[Lorrain88]
P. Lorrain, D. R. Corson, and F. Lorrain. Electromagnetic fields and waves: including electric circuits. Freeman, New York, 1988.